That's just a difference in how they display them. 239GB == 256GiBI also note, in CLI mode, the max size of a temporary plot file, doesn't exceed 239GB. Temporary plot files generated on the system running the GUI, always hit 256GB.
The GUI isn't ideal for plotting because it doesn't give you very fine grained control over scheduling the plot jobs, but it's just calling the CLI version itself, so the code used to create the plots is identical. Any slowdown in plotting is therefore due to the overhead of running the GUI itself (including the full node process, which does take a fair amount of resources to stay in sync).