I'm not 100% sure on how IB actually works when you're not using it in IP mode. My understanding is when you're using infiniband natively it becomes application dependent, no? Interestingly, the ScaleIO system requirements list an IBoIP network as one of their recommended requirements.
Anyway, Samba is a unix-side thing, not Windows, it provides interoperability between a Unix client and Windows CIFS/SMB shares, but doesn't necessarily provide support for all the same "bonus" protocols and technologies inherent in tech like SMB.
I think to still connect to Windows shares you need some kind of addressing protocol like IPv4. I could be totally wrong that though and would love for someone else to chime in.