After some further tests and catching back up with the thread here:
It seems my x16 riser in the first test has bit the dust, and was why the dGPU wasn't showing up. Oof (probably from messing around with the enable pins a while ago)
Testing with a known good riser, the T1000 worked again,
but the x8 network card would have the system get stuck on the Lenovo splash screen on boot.
I removed the card, went into BIOS and disabled ASPM (credit
@jja2000 for this reminder), saved and shut down, reinserted the card, it then booted up just fine and showed up in Proxmox.
The associated network adapters showed up as enp2XXXX instead of enp3XXXX when the card was working on the x4 riser, which should confirm that it is on the correct x16 PCIe bus now.
This is with the masked pin being 11 along the longer side of the CPU and 9 in from the shorter side.
Sorry for the blur, camera effects. the other should be decent.
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